Hiển thị các bài đăng có nhãn Peracetic acid. Hiển thị tất cả bài đăng
Hiển thị các bài đăng có nhãn Peracetic acid. Hiển thị tất cả bài đăng

Thứ Sáu, 7 tháng 8, 2015

Peracetic acid or Proxitane 15%

Peracetic acid or Proxitane 15%


Peracetic acid (also known as peroxyacetic acid, or PAA), is an organic compound with the formula CH3CO3H. This organic peroxide is a colorless liquid with a characteristic acrid odor reminiscent of acetic acid. It can be highly corrosive.

Peracetic acid is a weaker acid than the parent acetic acid, with a pKa ( acid dissociation constant ) of 8.2.

1 - Production

Peracetic acid is produced industrially by the autoxidation of acetaldehyde:


O2 + CH3CHO → CH3CO3H

It forms upon treatment of acetic acid with hydrogen peroxide, with the equilibrium constant dependent on the concentrations and conditions of reaction:


H2O2 + CH3CO2H is in equilibrium with CH3CO3H + H2O

As an alternative, acetyl chloride and acetic anhydride can be used to generate a solution of the acid with lower water content.

Peracetic acid is generated in situ by some laundry detergents. This route involves the reaction of tetraacetylethylenediamine (TAED) in the presence of an alkaline hydrogen peroxide solution. The peracetic acid is a more effective bleaching agent than hydrogen peroxide itself. PAA is also formed naturally in the environment through a series of photochemical reactions involving formaldehyde and photo-oxidant radicals.

Peracetic acid is always sold in solution with acetic acid and hydrogen peroxide to maintain the stability of the peracid. The concentration of the acid as the active ingredient can vary.

2 - Uses

The United States Environmental Protection Agency first registered peracetic acid as an antimicrobial in 1985 for indoor use on hard surfaces. Use sites include agricultural premises, food establishments, medical facilities, and home bathrooms. Peracetic acid is also registered for use in dairy/cheese processing plants, on food processing equipment, and in pasteurizers in breweries, wineries, and beverage plants. It is also applied for the disinfection of medical supplies, to prevent bio film formation in pulp industries, and as a water purifier and disinfectant. Peracetic acid can be used as a cooling tower water disinfect, where it prevents bio film formation and effectively controls Legionella bacteria. A trade name for peracetic acid as an antimicrobial is Nu-Cidex.

- Epoxidation

Although less active than more acidic peracids (e.g., MCPBA), peracetic acid in various forms is used for the epoxidation of various alkenes. Useful application are for unsaturated fats, synthetic and natural rubbers, and some natural products such as pinene. A variety of factors affect the amount of free acid or sulfuric acid (used to prepare the peracid in the first place).

3 - Niche uses

Peracetic acid will oxidize many metals, and is used for cleaning or creating a patina for artistic or protective purposes.

4 - Safety

Peracetic acid is a strong oxidizing agent (E = 1.762 V vs Ag/AgCl) and a primary irritant. Exposure to peracetic acid can cause irritation to the skin, eyes and respiratory system and higher or long-term exposure can cause permanent lung damage. In addition, there have been cases of occupational asthma caused by peracetic acid. The ACGIH has published (spring 2014) a STEL TLV for peracetic acid of 0.4 ppm, calculated as a 15 minute time weighted average (TWA). Currently there is no OSHA Permissible Exposure Limit (PEL) for peracetic acid. In 2010, the US-EPA published Acute Exposure Guidelines (AEGL) for peracetic acid.


- 1 - The concentration at which the general population will experience transient and reversible problems, such as notable discomfort, irritation, or certain asymptomatic non-sensory effects - 0.52 mg/m3 - 0.17 ppm

- 2 - The concentration that results in irreversible or other serious, long-lasting adverse health effects or an impaired ability to escape - 1.6 mg/m3 - 0.52 ppm

- 3 - The concentration that results in life-threatening health effects or death - 4.1 mg/m3 - 1.3 ppm

In comparison, the OSHA PEL for hydrogen peroxide (8 hour TWA) is 1.0 ppm. Peracetic acid has found widespread use in healthcare, food processing, and water treatment because of its broad antimicrobial properties. In order for employers to meet the ACGIH STEL TLV and comply with the General Duty Clause to provide a safe work environment, it is recommended that facilities using peracetic acid solution employ continuous monitors to provide an alert to employees if the concentration exceeds safe levels. This monitor is designed and installed so that it can automatically turn on additional ventilation as needed.

Concentrated peroxyacetic acid, an organic peroxide, explodes at 110 °C.
Wikipedia.org

Thứ Năm, 6 tháng 8, 2015

Proxitane 15:23




Tên gọi hóa chất: Proxitane 15:23, Proxitane 15% , hợp chất P3, hợp chất Peracetic Acid

Số CAS: 79-21-0

Thành phần hóa chất Proxitane 15:23: hợp chất của Paracetic acid (nồng độ 15%), acid acetic, Hydrogen Peroxyde ( nồng độ 23 % )

Hình thức hóa chất Proxitane 15:23: Dạng lỏng mùi nồng cay

Quy cách Proxitane 15:23: 30 kg/ can

Xuất xứ hóa chất Proxitane 15:23: Thái Lan

Công dụng hóa chất Proxitane 15:23: Proxitane là tên thương mại của sản phẩm hóa chất dạng lỏng, chuyên dùng cho việc sát khuẩn nhanh, sử dụng vệ sinh môi trường hoặc ở các giai đoạn cuối của qui trình vệ sinh đường ống thiết bị, dụng cụ chứa trong các nhà máy bia, sữa, nước giải khát và các ngành công nghiệp chế biến thực phẩm khác.

Ngoài ra Proxitane 15:23 còn là chất diệt khuẩn tốt cho môi trường vì nó không để lại dư lượng khi sử dụng. Nên nó được dùng thay thế cho BKC 80%, Formalin ( formol ) cho việc sát khuẩn ao nuôi tôm. Proxitane 15:23 cũng có thể cắt tảo độc trong ao nuôi, phân hủy chất hữu cơ dư thừa, đồng thời cung cấp oxy cho môi trường nước ao nuôi tôm.

Địa chỉ liên lạc mua hóa chất Proxitane 15:23:

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